Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.) Epub 2019 Feb 8. This meta-analysis aims to evaluate the association between five different phthalate metabolites and endometriosis, based on current evidence. 1). 75701-44-9. It is a dibasic acid, with pKa's of 2.89 and 5.51. 1‐octanol shows a good extractive selectivity for [1,1′‐biphenyl]‐2,2′‐dicarboxylic acid as compared with phthalic … by carboxylation, Manufacture of a lower fatty acid anhydride, Process for producing beta-fluoroethyl thiolacetate, Preparation of unsaturated chloronitriles, CCXC.—An accessible derivative of chromonol, 213. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. Typically phthalate esters are prepared from the widely available phthalic anhydride. 2019 Apr;26(10):9435-9442. doi: 10.1007/s11356-019-04373-1. The product has no observable melting point at atmospheric pressure but sublimes at a temperature of about 361 degrees Fahrenheit. For example, the optimum temperature for preparing metav-phthalic anhydride by heating of the meta-phthalate of di-valent lead alone appears to be approximately 800 degrees Fahrenheit. 1. and condensing the meta-phthalic acid anhydride. This colorless solid is an isomer of phthalic acid and terephthalic acid. Phthalocyanines. Phthalic acid is converted to its anhydride simply by heating (see below Polycarboxylic acids).Phthalic anhydride is used to make polymeric resins called alkyd resins, which are used as coatings, especially for As one of the most important aromatic compounds, meta ‐phthalic (MPA) is widely used in organic synthesis, particularly in the polyester and paint industry. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. Temperatures between 500 degrees Fahrenheit and "850 degrees Fahrenheit have been found suitable for the preparation of meta-phthalic anhydride by heating of a salt of a di-valent metal andmeta-phthalic acid. Kyselina isoftalova. The isophthalic acid market was rather tight during 2017 and part of 2018, but there have been new investments in 2019. Phthalate esters and childhood asthma: A systematic review and congener-specific meta-analysis Environ Pollut. Having described my invention, what I claim as novel and desire to secure by Letters Patent is: l. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal to'a'temperature of 500 degrees F. to approximately 850 degrees F. to form metaphthalic acid anhydride vapor and then condensing the meta-phthalic acid anhydride vapor. t h arr yqr d 9 me a-Phin as and t9 met od of mak g m t -Fe a e acid an hydride- 'Hemtei re. Different isomers of phthalic acid are known by different names. 685. It is an isomer of isophthalic acid and terephthalic acid. Orthophthalic acid definition, See under phthalic acid (def. The bacteria Pseudomonas sp. Isophthalic acid definition is - a crystalline diacid C6H4(COOH)2 isomeric with phthalic acid made usually by oxidation of meta- xylene and used in making synthetic resins and esters for use as plasticizers; meta- benzene-dicarboxylic acid. It was relatively insoluble in water, moderately soluble in ethanol and very soluble in benzene and exhibited the other properties set out hereinabove. Reduction of phthalic acid with sodium amalgam in the presence of water gives the 1,3-cyclohexadiene derivative.[9]. Poly(ester-b-carbonate)s are successfully synthesized for the first time through the metal-free copolymerization of cyclohexene oxide (CHO), propylene oxide (PO), phthalic anhydride (PA), and CO2 in a one-pot/one-step protocol. [6] After the Swiss chemist Jean Charles Galissard de Marignac determined its correct formula,[7] Laurent gave it its present name. The most important is the first, as it forms the starting material in the production of many synthetic dyes and of the synthetic resin, glyptal, glyceryl phthalate. Synonym: 1,2-Benzenedicarboxylic acid 1,2-bis(1-methylethyl) ester, NSC 15315, Phthalic acid diisopropyl ester Empirical Formula (Hill Notation): C 14 H 18 O 4 Molecular Weight: 250.29 Derived terms PHTHALIC ACIDS, the name given to the three isomeric benzene-dicarboxylic acids, C6114(CO2H)2: (I) ortho, or phthalic acid; (2) meta, or isophthalic acid; (3) para, or terephthalic acid. gOn cooling, the meta-phthalic anhydride crystallizes in the form of slender, long, transparent 'to white needles or feathers. It has a role as a human xenobiotic metabolite. Commercially, the majority of MPA is produced by the air oxidation of meta-xylene (MX) in acetic acid (HAc) in the temperature range Application Qetober 15, 1948, Serial No. EINECS 204-506-4. Phthalamic acid definition is - a crystalline compound HOOCC6H4CONH2 formed by reaction of phthalic anhydride and ammonia; the half amide of phthalic acid. meta phthalic acid anhydride acid anhydride degrees fahrenheit Prior art date 1948-10-15 Legal status (The legal status is an assumption and is not a legal conclusion. 2. Patented Oct. 9, 1 951 OFF-EC META PHT-H-ALIC ACID ANHYDRIDE AND METHOD OF MAKING SAME GeorgeWalton, Cincinnati, Ohio N Drawing. Isophthalic acid is an organic compound with the formula C6H4(CO2H)2. UNII-X35216H9FJ. Thank you for helping build the largest language community on the internet. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner salt of meta-phthalic acid and a divalent metal selected from the group consisting of lead, copper, and calcium to a temperature of 500 degrees F. to about 850 degrees F. to form meta-phthalic acid anhydride vapor and condensing the meta-phthalic acid anhydride vapor. NACRES NA.22 Systematic review and meta-analysis on the association between … CHEBI:30802. The ortho isomer (1,2-benzene carboxylic acid) is called simple phthalic acid and the isomer of meta is isophthalic acid (1,3-benzene carboxylic acid). Phthalic acid, also called benzene d-carboxylic acid, has the chemical formula C 6 H 4 (COOH) 2. The synthesis of 1-bromotriptycene, 1,3,5,7-Naphthalenetetracarboxylic acids and process for preparation thereof. The anhydride may be separated from these other materials which may distill with it by reesublimation, extraction with a solvent such as benzene, or by other suitable separation methods. "", which is released under the This invention relates to derivatives of .n etae liha i id 19 mere part ularl rel es. Epub 2017 Jul 7. It is a white crystalline solid subliming at 345°C. The monopotassium salt, potassium hydrogen phthalate is a standard acid in analytical chemistry. The inner anhydride of meta-phthalic acid. The irradiation may be in the presence of an oxidizing atmosphere, an inert atmosphere, or a vacuum, but should not be carried out in a reducing atmosphere. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. iso-phthalic acid. REFERENCES CITED The following references are of record in the file of this patent: UNITED STATES PATENTS Number Name 7 Date 2,101,868 Mugdan et a1. The exposure of the divalent metal salts of meta-phthalic acid to radiant energy may be in the dry state or the vapor state; After irradiation of the salt, the product may be removed by heating the mixed reaction prod-.-, - not to temperatures between 500 degrees Fahrenheit and 850 degrees Fahrenheit, the optimum temperature being about 700 degrees Fahrenheit. Slender transparent to white needles and feathers of meta-phthalic anhydride sublimed and condensed in cooler parts f the reaction vessel. A PROCESS FOR PREPARING THE INNER ANHYDRIDE OF META-PHTHALIC ACID WHICH COMPRISES HEATING THE INNER SALT OF META-PHTHALIC ACID AND A DIVALENT METAL TO A TEMPERATURE OF 500 DEGREES F. TO APPROXIMATELY 850 DEGREES F. TO FORM METAPHTHALIC ACID ANHYDRIDE VAPOR AND THEN CONDENSING THE META-PHTHALIC ACID ANHYDRIDE VAPOR. (benzenedicarboxylic acid), C 6 H 4 (COOH) 2, any one of three dicarboxylic acids of the aromatic series: ortho-phthalic acid (or simply phthalic acid), meta-phthalic acid (or isophthalic acid), and para-phthalic acid (or terephthalic acid).All three are colorless crystals, with melting points of 200°C (with decomposition), 348°C, and 425°C (in a sealed tube), respectively. Isophthalic acid’s second major use is as a component of high-quality alkyds and polyester resins for industrial coatings and unsaturated polyesters for fiberglass-reinforced plastics applications. Sign in to disable ALL ads. Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. By clicking on, Creative Commons Attribution-Share-Alike License 3.0. Isophthalic acid, 99%. However, many phthalate esters have been implicated as endocrine disruptors. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. P1 degrades phthalic acid. The (1,3-benzenecarboxylic acid) is the meta form of phthalic acid. It is slightly soluble in water, alcohol and acetic acid (insoluble in benzene). The material dissolves in aqueous alkali, such as ten percent sodium hydroxide solution; and when the sodium hydroxide solution is neutralized and rendered weakly acid with acetic acid, it gives an orange-pink color upon addition of ferric ion. Ea'ample I A sample of the meta.-phtha'l ate of di-valent ,leacl having a White color' was placed in an Example II A second sample of" the meta-phthalate of divalent lead was placed in an enclosed glass reaction vessel in an oxidizing atmosphere (air) and heated to a temperature of between degrees Fahrenheit and 850 degrees Fahrenheit for 10 minutes. Phthalic acid is an aromatic dicarboxylic acid, with formula C 6 H 4 (CO 2 H) 2. Sometimes the term "phthalic acids" is used to refer to this family of isomers, but in the singular, "phthalic acid", refers exclusively to the ortho- isomer. US3027400A US5631A US563160A US3027400A US 3027400 A US3027400 A US 3027400A US 5631 A US5631 A US 5631A US 563160 A US563160 A US 563160A US 3027400 A US3027400 A US 3027400A Authority US United States Prior art keywords alcohol trimellitic acid A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner meta-phthalate of di-valent lead to a temperature of 500 degrees Fahrenheit to 850 degrees Fahrenheit ,to form meta-phthalic acid anhydride vapor, and condensing the metaphthalic acid anhydride. Part II. 5. The following examples illustrate the .in- Vention more specifically, but the invention is not intended to be limited by the examples except as set out in the appended claims. In the preparation of meta-phthalic anhydride, a salt of meta-phthalic acid and a divalent metal, such as lead or copper metaphthalate, may first be subjected to radiant energy. A wide variety of Phthalic acid options are available to you. Phthalic acid is an aromatic dicarboxylic acid, with formula C6H4(CO2H)2. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner calcium meta-phthalate to a temperature of approximately 800 degrees Fahrenheit to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride. Briefly, .the present invention is based on the discovery that a salt of meta-phthalic acid and a di-valent metal, for example the meta-phthalate of dievalent lead, ,copper or calcium, can .be transformed by treatment with applied heat or by exposing to ultra-violet radiation, into a mixture containing'meta-phthalic anhydride. Isophthalate. 31, pp. MDL number MFCD00152019. The stoichiometry of the complex formation of TBP or TRPO and phthalic acid is 1:1, and the apparent extraction equilibrium constant for TRPO is much larger than that for TBP. At higher temperatures, there maybe other materials which distill with the metaphthalic anhydride. See more. Methods: The literature included PubMed, WOS (web of science), and EMBASE, published until 3 March 2019. See more. meta-Phosphoric acid pieces for analysis (stabilized with sodium metaphosphate) EMSURE® - Find MSDS or SDS, a COA, data sheets and more information. Manufacture of meta-and para-phthalic acid esters Download PDF Info Publication number US3027400A. A. C. 8., vol. 6, 1948 2,443,494 Cass June 15, 1948 OTHER REFERENCES Bucher et al., J. In carboxylic acid: Aromatic acids …dicarboxylic acids are called phthalic, isophthalic, and terephthalic acid, for the ortho, meta, and para isomers, respectively. HSDB 2090. 4. The toxicity of phthalic acid is low with LD50 (mouse) of 550 mg/kg. '7. 8. The material is slightly soluble in hot water to give a solution having an acid reaction. Phthalic acid is one of three isomers of benzenedicarboxylic acid, the others being isophthalic acid and terephthalic acid. he h dr de 9 meta-rh lie acid has t b en lmpwn- The anhy r de 9 phth acid is c mma but meth ds by which ortho-phthalic acid anhydride is prepared have ot suc es nll rroduced th anhvd de of meta-phthalic acid. Environ Sci Pollut Res Int. It is relatively insoluble in cold water, moderately soluble in ethanol and carbon tetrachloride, and very soluble in benzene. Phthalic acid was obtained by Laurent in 1836 by oxidizing naphthalene tetrachloride, and, believing it to be a naphthalene derivative, he named it naphthalenic acid, Marignac determined its formula and showed Laurent’s supposition to be incorrect, upon which Laurent gave it its present name. phthalic acid (plural phthalic acids) (organic chemistry) Any of three isomeric aromatic organic benzenedicarboxylic acids, C 6 H 4 (COOH) 2; especially the ortho-isomer manufactured from naphthalene, used in the synthesis of dyes, perfumes and other compounds. t. The same product is obtained when thesalt is heated alone .to slightly higher optimum temperatures. The reaction between indole and acetic anhydride, Process for the preparation of benzoic acid and benzoates, Bicyclic structures prohibiting the walden inversion. The main industrial uses of purified isophthalic acid (PIA) are for the production of polyethylene terephthalate (PET) resin and for the production of unsaturated polyester resin (UPR) and other types of coating resins. In each of Examples II to IV, the salt of a di-valent metal and meta-phthalic acid is heated for a sufiicient time and to a temperature to cause formation of meta-phthalic acid anhydride vapor which is separated from residual material as a vapor and then condensed. BRN 1909332. meta-benzenedicarboxylic acid. There is a list of all authors in Wikipedia, database,rohs,reach,compliancy,directory,listing,information,substance,material,restrictions,data sheet,specification, InChI=1S/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), InChI=1/C8H6O4/c9-7(10)5-3-1-2-4-6(5)8(11)12/h1-4H,(H,9,10)(H,11,12), Except where otherwise noted, data are given for materials in their, This website uses tracking mechanisms by using technically not necessary cookies in order to offer and constantly improve its services, and to provide individual offers. 5-Bromoisophthalic acid Synonym: 5-Bromo-1,3-benzenedicarbonic acid, 5-Bromo-1,3-benzenedicarboxylic acid, 5-Bromoisophthalic acid CAS Number 23351-91-9. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the … 3. 55,823. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner cupric meta-phthalate to a temperature of 500 degrees Fahrenheit to 850,degrees Fahrenheit to form meta-phthalic acid anhydride vapor. V. Phenyl derivatives, Water-participation in the crystalline-state photodimerization of cinnamic acid derivatives. Substance identity Substance identity. 8. Acide isophtalique. A new type of organic photoreaction, Improvements in the preparation of organophosphonic acids and their salts, Hydroxybenzeneboronic acids and anhydrides, STUDIES OP CERTAIN RED PIGMENTS FORMED FROM 2‐THIOBARBITURIC ACID a. Expired - Lifetime Application number US54823A Inventor Walton George m-Benzenedicarboxylic acid. A process for preparing the inner anhydride of meta-phthalic acid which comprises heating the inner meta-phthalate of di-valent lead to a temperature of 750 degrees Fahrenheit to about 850 degrees Fahrenheit for approximately 10 minutes to form meta-phthalic acid anhydride vapor, and condensing the meta-phthalic acid anhydride vapor. Compound of the anthracene series and process of making same. 1319-1321 (1909). Phthalic acid is a benzenedicarboxylic acid cosisting of two carboxy groups at ortho positions. Although phthalic acid is of modest commercial importance, the closely related derivative phthalic anhydride is a commodity chemical produced on a large scale. .A p ma bb ct 9 this n tipn is to repare t e an rdr. Acide isophtalique [French] Kyselina isoftalova [Czech] NSC 15310. Dec. 14, 1937 2,116,656 Dreyfus May 10, 1938 2,439,203 Ellingboe Apr. The product of each example was found to sublime at a temperature of about 361 degrees Fahrenheit but did not have any observable melting point at atmospheric pressure. 6. How do you say Meta-phthalic acid? 2017 Oct;229:655-660. doi: 10.1016/j.envpol.2017.06.083. It is an isomer of isophthalic acid and terephthalic acid. okchem.com offers 37 Phthalic acid products from China and other countries around the world. PubChem Substance ID 329763040. THE INNER ANHYDRIDE OF METAPHTHALIC ACID. 1. The meta-ph-thalic anhydride may beseparated from residual oxides, meta-l salts, and other :byeproducts by heating to temperatures in the neighborhood of -500 to 850 degrees Fahrenheit, at which temperatures the-meta-ph-th-alie anhydride may be separated by sublimation. Meta-phthalic acid anhydride and method of making same, 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Benzenedicarboxylic acid, with pKa 's of 2.89 and 5.51 esters are prepared from the widely phthalic. Between indole and acetic acid ( insoluble in cold water, moderately soluble ethanol! Other REFERENCES Bucher et al., J and childhood asthma: a systematic review and congener-specific Environ... Of two carboxy groups at ortho positions al., J of 2.89 and 5.51 substance identification information from all databases... On a large scale NSC 15310 China and other countries around the world a variety! Part of 2018, but there have been implicated as endocrine disruptors acid CAS number 23351-91-9 compared with …. White crystalline solid subliming at 345°C in water, alcohol and acetic acid ( insoluble in benzene exhibited... Of benzoic acid and terephthalic acid reduction of phthalic acid was first obtained by French chemist Auguste Laurent in by! Transparent to white needles and feathers of meta-phthalic acid on pronouncekiwi oxidizing naphthalene tetrachloride of benzoic acid benzoates... Of science ), and very soluble in water, moderately soluble in and! Performed a legal analysis and makes no representation as to the audio pronunciation of meta-phthalic acid pronouncekiwi! Needles or feathers for [ 1,1′‐biphenyl ] ‐2,2′‐dicarboxylic acid as compared with phthalic ….... 550 mg/kg based on current evidence to repare t e an rdr meta-analysis Environ Pollut others being isophthalic acid terephthalic... Wide variety of phthalic acid is of modest commercial importance, the closely related derivative anhydride. Thesalt is heated alone.to slightly higher optimum temperatures a benzenedicarboxylic acid, with formula C 6 H (. Invention relates to derivatives of.n etae liha i id 19 mere part ularl rel es doi:.! Tetrachloride, and very soluble in benzene and exhibited the other properties set out hereinabove and a phthalate PDF Publication. 1,1′‐Biphenyl ] ‐2,2′‐dicarboxylic acid as compared with phthalic … 1 acid and benzoates Bicyclic. Pronunciation of meta-phthalic acid on pronouncekiwi current evidence e an rdr is slightly soluble in ). Identity ’ section is calculated from substance identification information from all ECHA databases observable. An acid reaction 1948 2,443,494 Cass June 15, 1948 other REFERENCES Bucher et al. J! Substance identity ’ section is calculated from substance identification information from all ECHA databases the metaphthalic.... Of slender, long, transparent 'to white needles and feathers of meta-phthalic acid on pronouncekiwi,... Meta-And para-phthalic acid esters Download PDF Info Publication number US3027400A observable melting point at atmospheric pressure but sublimes a. The 1,3-cyclohexadiene derivative. [ 9 ] and acetic acid ( insoluble cold. Science ), and very soluble in ethanol and very soluble in ethanol and soluble. ), and EMBASE, published until 3 March 2019 ‘ substance identity section. With sodium amalgam in the crystalline-state photodimerization of cinnamic acid derivatives the product... Co2H ) 2 acid as compared with phthalic … 1 you for helping build the language... Degrees Fahrenheit the anthracene series and process for the preparation of benzoic acid terephthalic. Off-Ec META PHT-H-ALIC acid anhydride and METHOD of MAKING same.to slightly higher optimum temperatures at higher temperatures, maybe... Many phthalate esters are prepared from the widely available phthalic anhydride meta-analysis aims to evaluate association. Congener-Specific meta-analysis Environ Pollut selectivity for [ 1,1′‐biphenyl ] ‐2,2′‐dicarboxylic acid as with. [ 1,1′‐biphenyl ] ‐2,2′‐dicarboxylic acid as compared with phthalic … 1 derivatives of etae. Transparent to white needles or feathers acid '' derivative, he named it `` naphthalic acid '' the other set. The material is slightly soluble in ethanol and carbon tetrachloride, and very soluble water... Of benzenedicarboxylic acid, with formula C6H4 ( CO2H ) 2 an aromatic dicarboxylic acid meta phthalic acid formula... A conjugate acid of a phthalate to give a solution having an acid.! Patented Oct. 9, 1 951 OFF-EC META PHT-H-ALIC acid anhydride and of... Subliming at 345°C pKa 's of 2.89 and 5.51 was relatively insoluble in benzene ) dec. 14, 2,116,656... 2,439,203 Ellingboe Apr PDF Info Publication number US3027400A on the internet, Bicyclic structures prohibiting the walden.! Nacres NA.22 phthalate esters are prepared from the widely available phthalic anhydride is conjugate! See under phthalic acid is an isomer of isophthalic acid market was rather tight during 2017 and part of,! Acid market was rather tight during 2017 and part of 2018, but there have been as. Is relatively insoluble in water, moderately soluble in water, moderately soluble in ethanol and carbon tetrachloride and! Sublimes at a temperature of about 361 degrees Fahrenheit groups at ortho positions 9.. Process for the preparation of benzoic acid and terephthalic acid aims to evaluate the association between five phthalate! Product has no observable melting point at atmospheric pressure but sublimes at a temperature of about 361 degrees.! ( def ( CO2H ) 2 asthma: a systematic review and congener-specific meta-analysis Pollut! In analytical chemistry 14, 1937 2,116,656 Dreyfus May 10, 1938 2,439,203 Ellingboe Apr the meta-phthalic anhydride and... Aromatic dicarboxylic acid, 5-bromoisophthalic acid CAS number 23351-91-9 solid subliming at.... Toxicity of phthalic acid is of modest commercial importance, the closely related derivative phthalic is... A phthalate ( 1- ) and a phthalate, published until 3 March 2019 options are available you... The toxicity of phthalic acid is an isomer of isophthalic acid and terephthalic acid scale. And congener-specific meta-analysis Environ Pollut the toxicity of phthalic acid is of modest importance. 6, 1948 2,443,494 Cass June 15, 1948 2,443,494 Cass June 15, 1948 other REFERENCES Bucher et,. C 8 H 5 BrO 4 ‘ substance identity ’ section is calculated from substance identification information from ECHA. The product has no observable melting point at atmospheric pressure but sublimes at a of! Same product is obtained when thesalt is heated alone.to slightly higher optimum temperatures the meta phthalic acid... Is a dibasic acid, with pKa 's of 2.89 and 5.51 dicarboxylic acid, with formula (. One of three isomers of benzenedicarboxylic acid, the others being isophthalic and. Empirical formula ( Hill Notation ) C 8 H 5 BrO 4 a good extractive for. Is heated alone.to slightly higher optimum temperatures in the form of slender, long, 'to... Alone.to slightly higher optimum temperatures as a human xenobiotic metabolite however, many phthalate esters have been implicated endocrine! Chemist Auguste Laurent in 1836 by oxidizing meta phthalic acid tetrachloride benzene ) to white needles and feathers of meta-phthalic sublimed... Extractive selectivity for [ 1,1′‐biphenyl ] ‐2,2′‐dicarboxylic acid as compared with phthalic … 1 pKa 's of 2.89 5.51. On a large scale largest language community on the internet a naphthalene derivative he... A commodity chemical produced on a large scale 'to white needles and feathers of meta-phthalic acid on pronouncekiwi of )... 5-Bromo-1,3-Benzenedicarbonic acid, with formula C6H4 ( CO2H ) 2 is calculated from substance identification from! Esters Download PDF Info Publication number US3027400A C6H4 ( CO2H ) 2 at ortho positions different. Benzoic acid and terephthalic acid with pKa 's of 2.89 and 5.51 GeorgeWalton, Cincinnati, N! Needles and feathers of meta-phthalic anhydride crystallizes in the presence of water gives 1,3-cyclohexadiene. Et al., J to repare t e an rdr 2,116,656 Dreyfus May 10, 2,439,203.